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A. Frank-Kamenetski in Zh. Fiz. Khim. 12, 100 (1938). BIFUNCTIONAL CATALYSIS J. H. Sinfelt Esso Research and Engineering Cornpony, linden, New Jersey ........................ I. Introduction atal ysts . . . . . . . . A. General Description of Platinum Reforming Catalysts . . . . . . . . B. Characterization of the Metal Component . . C. Properties of the Acidic Component . , . . . . . . . . . . . . . . 111. Nature of Reactions Occurring over Bifunctional Catalysts .

Combust. 6th Yale Univ. 1966 p. 213 (1957). Reinhold, New York. C4. Campbell, E. , Heinen, F. , Symp. Combust. 9th Cornell Univ. Y. 1962 p. 72 (1963) Academic Press, New York. C5. Chaiken, R. , Combust. Flame 3, 285 (1959). C6. , and Friedricks, K. ” Wiley (Interscience), New York, 1948. C7. Courtney, W. , Symp. Combust. , 1962 p. 799 (1963). Academic Press, New York. Dl. de Sendagorta, J. , Combust. Flame 5, 305 (1961). D2. , and Williams, A,, Sump. Combust. , Ithaca, N. , 1968 p. 576 (1963). Academic Press, New York.

Treatment of alumina with 42 J. H. SINFELT halogens such as C1 or F tends to make the acidic properties of alumina more pronounced, in the sense that it increases the activity of alumina for the catalysis of typical acid-catalyzed reactions, such as the skeletal isomerization of olefins and various cracking reactions of hydrocarbons (h43, R2, 53). It has been suggested that incorporation of halogens in the surface of alumina involves partial replacement of OH groups, known to exist on alumina (P2), by C1 or F.

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