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19] Pasteur, L. Acad. , 1848, 26, 535. : Termal. Anal. 1988, 33, 1241. : J. Chem. Soc. Perkin Trans 2, 2000, 149. : Tetrahedron: Asymm. 2000, 11, 809. ; Simon, H;. : Chirality 2001, 13, 29. : PhD disz. 2003 [25] a). ; Fogassy, E. b). Hung. Pat. no. ; Böcskei, Zs. Chirality, 1994, 6, 314 [27] Kassai, Cs: PhD diss. : Tetrahedron Letters, 1994, 35, 257260 . :. Tetrahedron: Asymmetry. 2008, 19, 1587. ; J. Pract. Chem. 1986, 336, 628. : J. Mol. Structure 1986, 147, 143. : Tetrahedron, 1985 41, 2841.
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In the simplest cases the generally used methods follow the first ever resolution by salt formation accomplished by Pasteur (fractionated precipitation method). In this case the racemic compound and the resolving agent are dissolved in a solvent, in a molar equivalent amount. The less soluble diastereoisomeric salt crystallizes (during cooling) and it can be separated from the other diastereoisomeric salt (remained in solution) by filtration. The enantiomeric mixtures are isolated from the diastereoisomers and they are enriched to the desired ee values by applying one of the previously discussed methods.