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By Peter William Atkins, Julio De Paula

With its emphasis on actual rules, cautious exposition of crucial arithmetic, and priceless pedagogy, components of actual Chemistry is the appropriate textual content for the one-semester actual chemistry path. the recent version bargains much more scholar and teacher help, now in a stunning full-color presentation.

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Extra resources for Elements of physical chemistry, 5th Edition

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7). This function approaches zero more rapidly as a increases. 9 8 7 6 5 0 0 x 1 2 3 4 3 e–x e–x 2 2 1 0 –5 –4 –3 –2 –1 0 x 1 2 3 4 5 Fig. 7 The exponential function, e−x, and the bell-shaped 2 Gaussian function, e−x . Note that both are equal to 1 at x = 0 but the exponential function rises to infinity as x → −∞. The enlargement on the right shows the behaviour for x > 0 in more detail. • A Gaussian function, a function of the form e−ax , also starts off at 1 when x = 0 and decays to zero as x increases, however, its decay is initially slower but then plunges down to zero more rapidly than an exponential function (Fig.

4140 dm3 mol−1. 2 Using the perfect gas law Here we review three elementary applications of the perfect gas equation of state. The first is the prediction of the pressure of a gas given its temperature, its chemical amount, and the volume it occupies. The second is the prediction of the change in pressure arising from changes in the conditions. The third is the calculation of the molar volume of a perfect gas under any conditions. 1). 25 g of nitrogen gas in a flask of volume 250 cm3 at 20°C. 15 to the Celsius temperature).

The precise form of the distribution was worked out by James Clerk Maxwell towards the end of the nineteenth century, and his expression is known as the Maxwell distribution of speeds. 16) This formula was used to calculate the numbers quoted above. 16 looks complicated, its features can be picked out quite readily. One of the skills to develop in physical chemistry is the ability to interpret the message carried by equations. Equations convey information, and it is far more important to be able to read that information than simply to remember the equation.

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