By Chao-Jun Li, James H Clark, George A Kraus, Andrzej Stankiewicz, Peter R Seidl, Yuan Kou, Tsugio Kitamura, Zhiping Li, Christophe Darcel, Guojun Deng, Brenton De Boef, M Sodeoka, Kenichiro Itami, Oliver Basle, Corey Stephenson, Matthew Todd
The C-C bond is a uncomplicated development block in chemistry, and its formation is usually step one in the direction of construction extra complicated molecules. The direct iteration of C-C bonds from C-H by means of cross-dehydrogenative-coupling (CDC) reactions in 2003 has offered a paradigm shift in the direction of extra effective man made layout, and during the last decade this has develop into a sizzling subject in eco-friendly Chemistry.
This edited booklet provides a precis of the newest advancements within the formation of C-C bonds direct from varied C-H bonds through oxidative dehydrogenative couplings. The editor, (CJ Li, McGill collage) has pioneered numerous copper and organo-catalyzed CDC reactions inside his eco-friendly Chemistry and natural Synthesis workforce, and has introduced jointly services from the world over to provide some of the CDC reactions getting used this day. practising man made chemists looking to increase the potency in their reactions will make the most of this method, whereas scholars and people wishing to undertake those reactions will achieve a radical figuring out of the sphere. The conclusions provided on the finish of the e-book will encourage all readers to the longer term possibilities within the field.
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Extra resources for From C-H to C-C bonds : cross-dehydrogenative-coupling
Direct arylations and oxidative olefinations date back to the pioneering investigations of van Helden and Verberg,60 and Fujiwara and Moritani61 as well as other contributors62 who demonstrated that aromatic C–H bonds are eﬃciently activated for coupling with a second sp2 C–H bond in the presence of stoichiometric quantities of Pd salts. 35). The groundbreaking work of Shue,63 de Vries and van Leeuwen64 and others65 on oxidative olefinations and the contributions of Lu,66 Fagnou,67 DeBoef68 and others69 on direct arylations laid the foundation for the development of an impressive number of transition-metal-catalyzed selective crossdehydrogenative sp2 C–H couplings.
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