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Extra resources for General and Synthetic Methods Volume 1

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93 The products of oxidation of a variety of olefins by tetrachloroauric acid in methanol have been investigated. Gold(rrr) acts as an electrophile and gives an organometallic adduct which decomposes by heterolysis of the C-Au bond. A comparison made between the products resulting from oxidations with thallium(rrr) and lead(rv) showed that the differences could be explained either in terms of 93 K. B. Sharpless, A. 0. Chong, and K. Oshima, J . Org. , 1976, 41, 177. General and Synthetic Methods 24 TsNCINa,3Hz0 + "'I":,:, + NaCl + RZ Procedure A : Chloramine T, Bu'OH, OSO, , 60 ?

J. S. Baum and H. G . Viech, J . Org. , 1976, 41, 183. A . J. Rudicskas and T. L. Hallar, J . Org. , 1976, 41, 2411.

W. Shull, E. R. Fogel, R. J. Ruffner, and J . R. Falck, J. Org. , 1976, 41, 3218. B. M. Trost and A. J. Bridges,J. Arner. Chem. , 1976, 98, 5017. L. E. Overrnan, G. F. Taylor, and P. J. Jessup, Tetrahedron Letters, 1976, 3089. W. G. Dauben and H. 0. Krabbenhoft, J . Amer. Chem. , 1976,98, 1992. R. F. C . Brown, F. W. Eastwood, and G. L. McMullen, J . Arner. Chem. ,1976,98, 7421. J. S. Baum and H. G . Viech, J . Org. , 1976, 41, 183. A . J. Rudicskas and T. L. Hallar, J . Org. , 1976, 41, 2411.

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