By Zhan-Ting Li, Li-Zhu Wu
This ebook covers the advances within the reports of hydrogen-bonding-driven supramolecular structures revamped the earlier decade. it truly is divided into 4 elements, with the 1st introducing the fundamentals of hydrogen bonding and demanding hydrogen bonding styles in resolution in addition to within the stable nation. the second one half covers molecular popularity and supramolecular buildings pushed through hydrogen bonding. The 3rd half introduces the formation of hole and titanic macrocycles directed through hydrogen bonding, whereas the final half summarizes hydrogen bonded supramolecular polymers.
This ebook is designed to collect in one quantity the various vital elements of hydrogen bonding supramolecular chemistry and may be a necessary source for graduates and researchers operating in supramolecular and comparable sciences.
Zhan-Ting Li, PhD, is a Professor of natural Chemistry on the division of Chemistry, Fudan collage, China.
Li-Zhu Wu, PhD, is a Professor of natural Chemistry on the Technical Institute of Physics and Chemistry, chinese language Academy of Sciences, China.
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Extra info for Hydrogen Bonded Supramolecular Structures
The AADADD-typed HB-218 is one example. -W. Zhang et al. Aromatic hydrazide derivatives connected by flexible linkers can also form similar homo- and heteroduplexes . The DAADDAAD-ADDAADDA-typed HB-219 is one of the few examples of octuple hydrogen bonding motifs formed by two different monomers . The two monomers themselves form sextuple hydrogen bonding homodimers (HB-220 and HB-221). Upon mixing, the octuple hydrogen bonding heterodimer is generated selectively. The stability of the three binding motifs was not investigated quantitatively.
The importance of weak C–H···F–C hydrogen bonds was observed in the absence of any strong hydrogen bond donor. Crystal packing analysis of a series of fluorine substituted isoquinolines was observed to be stabilized by mainly C–H···F hydrogen bonds along with C–F···F–C and C–F···π in the absence of any other relatively stronger intermolecular forces such as hydrogen bonding, C–H···π or π···π interactions [75, 76]. The detailed analysis of eighteen crystal structures of fluorine substituted phenylmaleimides and corresponding phthalimides (Fig.
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