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Additional resources for Nanostructured Oxides
73]; © Wiley-VCH Verlag GmbH & Co. KGaA. quickly through fusion and redispersion processes (106–108 m−1 s−1). Consequently, PEIs reacted with silicic acid from a tetramethylorthosilicate (TMOS) precursor produced silica nanoparticles with a size and structure control that was dependent on the size of the RM . 2) in water. 22). Consequently, it was expected that PEI would provoke a similar pH dependence when reacted with the RM. However, when PEI and silicic acid were incorporated into the RMs prepared in iso-octane, the initial pH of the amine solution was negligible in terms of controlled silica growth.
One such technique – piezoelectric inkjet printing – is a noncontact method that employs a user-controlled waveform to deposit known amounts of material onto a variety of substrates . With the advent of such readily available deposition techniques, even more metal oxides could be printed on the 2-D scale [88, 93]. The constrained and unconstrained syntheses of metal oxides reported to date can now be incorporated with these newer technologies to bridge the in vitro and macromolecular worlds of biology and materials science, together expanding new frontiers in nanomaterial design.
These changes in morphology suggest that different types of nanostructures could be formed simply by agitating the reaction mixture at different frequencies. Titania (TiO2) has been synthesized incorporating a variety of peptides, including R5 peptide, PLL, spermidine and spermine [88, 89]. Although it is not as naturally abundant as silica, TiO2 has been identiﬁed in the comb of the hornet Vespa orientalis, the test (skeleton) of the foraminiferan Bathysiphon argenteus, and also in leukocytes and osteosarcomas in humans .