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L. R. C. Parker, J. Chem. Phys. 47, 1148 (1967). [22] D. Stensfield, Proc. Phys. Soc. 72, 854 (1958). T. B. Stewart, and M. Jahangiri, J. Phys. Chem. Ref. Data 15, 735 (1986). [24] IUPAC International Thermodynamic Tables of the Fluid State – 9, Oxygen (Blackwell, Oxford, London, Edinburgh, Boston, Palo Alto, Melbourne, 1987). B. Vargaftik, Tables on the Thermophysical Properties of Liquids and Gases (Wiley, New York, 1975), 2nd ed. [26] U. Zetzmann and W. Wagner, J. Phys. Chem. Ref. Data 20, 1061 (1991).

Skripov, Crystallogr. (Russian) 27, 358 (1982). Yu. Tonkov, Phase Diagrams of Compounds at High Pressure (Nauka, Moscow, 1983) (in Russian). Yu. Tonkov, Phase Transformations of Compounds at High Pressure (Nauka, Moscow, 1988) (in Russian). P. I. R. T. Yakovlev, Thermophysical Properties of Mercury (Izdatelstvo Standartov, Moscow, 1971) (in Russian). E. G. H. Stout, J. Phys. Chem. Solids 49, 945 (1988). D. Urlin, Zh. Eksp. Teor. Fiz. (Russian) 49, 485 (1965). W. C. Kennedy, J. Phys. Chem. Solids 37, 795 (1976).

1 Introduction Phase transformations play an important role in a variety of processes ranging from nucleation and growth in the atmosphere [1, 2], nucleation and growth in expanding gases [3, 4], bubble formation in liquids [5, 6] and phase formation in solids [7–10] to phase transitions in nuclear matter [11–14] and in the early universe [15]. , Refs. [5,21–23]). According to the classical picture, the phase transformation proceeds via the formation of clusters representing precursors of the newly evolving phase.

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