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All rights reserved. About this PDF file: This new digital representation of the original work has been recomposed from XML files created from the original paper book, not from the original typesetting files. Page breaks are true to the original; line lengths, word breaks, heading styles, and other typesetting-specific formatting, however, cannot be retained, and some typographic errors may have been accidentally inserted. Please use the print version of this publication as the authoritative version for attribution.

About this PDF file: This new digital representation of the original work has been recomposed from XML files created from the original paper book, not from the original typesetting files. Page breaks are true to the original; line lengths, word breaks, heading styles, and other typesetting-specific formatting, however, cannot be retained, and some typographic errors may have been accidentally inserted. Please use the print version of this publication as the authoritative version for attribution.

Many of these “metal cluster” compounds consist of several metal atoms bound to each other in the “core” of the molecule with carbon monoxide molecules chemically attached on the periphery. These metal carbonyls have formulas Mx(CO)y, and x can be made very large. The world's record as of this writing is a platinum . compound with x=38, At the same time, very low temperature techniques are revealing the structures and chemistry of small aggregates containing only metal ions or atoms (“naked clusters”).

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