Download The Metal - Carbon Bond: Volume 2 (1985) PDF

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Content:
Chapter 1 Electrochemical cleavage of metal—carbon bonds (pages 1–24): C. J. Pickett
Chapter 2 Heterolytic cleavage of major team metal—carbon bonds (pages 25–149): Michael H. Abraham and Priscilla L. Grellier
Chapter three Homolytic cleavage of metal—carbon bonds: teams I to V (pages 151–218): Philip J. Barker and Jeremy N. Winter
Chapter four Insertions into major team metal–carbon bonds (pages 219–338): J. L. Wardell and E. S. Paterson
Chapter five Insertions into transition metal—carbon bonds (pages 339–400): John J. Alexander
Chapter 6 Nucleophilic assault on transition steel organometallic compounds (pages 401–512): Louis S. Hegedus
Chapter 7 Electrophilic assault on transition steel ?1?organometallic compounds (pages 513–558): M. D. Johnson
Chapter eight Transition metal—carbon bond cleavage via ??hydrogen removing (pages 559–624): R. J. Cross
Chapter nine Oxidative addition and reductive removal (pages 625–787): J. ok. Stille
Chapter 10 constitution and bonding of major team organometallic compounds (pages 789–826): John P. Oliver

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Sample text

Lloyd, and J. A. McCleverty, J. Chem. , 1743 (1973). 85. J. Chatt, C. T. Kan, G. J. Leigh, C. J. Pickett, and D. R. Stanley, J. Chem. , 2032 (1980). 86. P. M. Triechel and G. E. Dureen, J . Organomet. , 39, C20 (1972). 87. P. M. Triechel, G. E. Dureen, and H. 3. Mueh, J . Organornet. , 44, 339 (1972). 88. C. J . Pickett and D. Pletcher, J. Organomet. , 102,327 (1975). 89. E. 0. Fischer, F. J. Gamnel, J. 0. Besenhard, A. Frank and D. Neugebauer, J. Organornet. , 191,261 (1980). 90. R. Riedce, H.

INTRODUCTION A. General Introduction T h e non-transition metal-carbon bond is polarized i n tlic sense M"'-C' a n d thus heterolytic cleavage of such a b o n d can formally t a k e place by electrophilic attack at t h e carbon centre, although a n elcctrophile will actually first interact with t h e filled m e t a l - c a r b o n cr-bond. The main typcs of electrophilic reagents that have becn studied in some detail are t h e halogens, various acids, and metal salts a n d esters; t h c latter reagents lead to t h e well known mctal-for-metal exchange reactions.

Connelly, R . A. Kelly, M. D. Kitchen, and P. Woodwsrd, J. Chew. , 1710 (198Oj. 58. N. G. Connelly, R. L. Kelly, and M. W. Whitelcy, J . Ckeni. , 34 (1981). 59. R. E. Dessey and R. L. Pohl, J . Am. Chetn. ,90, 1995 (1968). 60. R. E. Dcssy, F. E. Stary, R. I3. King, and M. Waldrop, J. Ani. Ctieni. , 88,471 (1966). 61. R. E. Dcssy, R. B. King, and M. Waldrop, J . Am. Chetn. , 88, 5112 (1966). 62. R. E. Dessy, J . C. Charkoudian, T. P. Abclo, and A. L. Rhcirigold, J . Am. Chetn. , 92, 3947 (1970).

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